Utilization of Kapok Seed Oil (Ceiba pentandra) for Biodiesel Production using MgO/CaO Bimetallic Oxide Catalysts
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Published
Nov 1, 2017
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Abstract
The utilization of renewable energy resources received much attention due to the rapid depletion of fossil fuels. The production of biodiesel using homogeneous catalysts has several disadvantages such as complexity of separation process which leads the high production cost. Magnesium and calcium oxide (MgO/CaO) heterogeneous catalysts can be used to overcome these weaknesses. This study uses kapok seed oil (Ceiba pentandra) as the feedstock of biodiesel production. MgO/CaO catalysts were calcined at 950ᵒC for 5 hours. The catalyst activities were studied in various composition of MgO (0.5-2 wt.%) to determine the highest activity. The transesterification was carried out in various temperature (50-70ᵒC) in batch reactor. The highest yield was achieved for 0.5 wt.% of MgO composition in the catalyst with the yield of 59.58%. In the effect of temperature and reaction time study, the highest yield of 55.22% was achieved at temperature of 70ᵒC for 75 minutes.
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How to Cite
SANTOSO, F. Agoes et al.
Utilization of Kapok Seed Oil (Ceiba pentandra) for Biodiesel Production using MgO/CaO Bimetallic Oxide Catalysts.
Proceedings of the International Conference on Green Technology, [S.l.], v. 8, n. 1, p. 209-215, nov. 2017.
ISSN 2580-7099.
Available at: <http://conferences.uin-malang.ac.id/index.php/ICGT/article/view/542>. Date accessed: 25 apr. 2024.
doi: https://doi.org/10.18860/icgt.v8i1.542.
Section
Chemistry
References
[1] Hasan MH, Mahlia TMI, Nur H. A review on energy scenario and sustainable energy in Indonesia. Renew. Sustainable Energy Rev. [Internet]. 2012 Feb [cited 2013 Aug 2];16(4):2316-28. Available from: http://www.sciencedirect.com/science/article/pii/S1364032111005995 DOI: 10.1016/j.rser.2011.12.007
[2] Leung DYC, Wu X, Leung MKH. A review on biodiesel production using catalyzed transesterification. Appl. Energy. [Internet]. 2010 Apr [cited 2013 Jan 15];87(4):1083-95. Available from: http://www.sciencedirect.com/science/article/pii/S0306261909004346 DOI: 10.1016/j.apenergy.2009.10.006
[3] Maceiras R, Rodrı´guez M, Cancela A, Urréjola S, Sánchez A. Macroalgae: Raw material for biodiesel production. Appl. Energy. [Internet]. 2011 Oct [cited 2013 Jun 14]; 88(10):3318-23. Available from: http://www.sciencedirect.com/science/article/pii/S0306261910004903 DOI: 10.1016/j.apenergy.2010.11.027
[4] Asri NP, Machmudah S, Wahyudiono, Suprapto, Budikarjono K, Roesyadi A, et al. Palm oil transesterification in sub- and supercritical methanol with heterogeneous base catalyst. Chem. Eng. Process. [Internet]. 2013 Oct [cited 2014 Jun 14]; 72:63-7. Available from: http://www.sciencedirect.com/science/article/pii/S0255270113001670 DOI: 10.1016/j.cep.2013.07.003
[5] Suganya T, Nagendra Gandhi N, Renganathan S. Production of algal biodiesel from marine macroalgae Enteromorpha compressa by two step process: Optimization and kinetic study. Bioresour. Technol. [Internet]. 2013 Jan [cited 2014 Mei 14]; 128: 392-400. Available from: http://www.sciencedirect.com/science/article/pii/S0960852412015702 DOI: 10.1016/j.biortech.2012.10.068
[6] Lam MK, Lee KT, Mohamed AR. Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnol. Adv. [Internet]. 2010 Jul [cited 2013 Dec 14]; 28(4):500-18. Available from: http://www.sciencedirect.com/science/article/pii/S0734975010000388 DOI: 10.1016/j.biotechadv.2010.03.002
[7] Sivakumar P, Sindhanaiselvan S, Gandhi NN, Devi SS, Renganathan S. Optimization and kinetic studies on biodiesel production from underutilized Ceiba Pentandra oil. Fuel. Internet]. 2013 Jan [cited 2013 Feb 19]; 103:693-8. Available from: http://www.sciencedirect.com/science/article/pii/S0016236112004498 DOI: 10.1016/j.fuel.2012.06.029
[8] Putri EMM, Rachimoellah M, Santoso N, Pradana F. biodiesel production from kapok seed oil (Ceiba pentandra) through the transesterification process by using CaO as catalyst. Global Journal of Researches in Engineering [Internet]. 2012 Aug [cited 2013 Feb 22]; 12(2):7-12. Available from: https://globaljournals.org/GJRE_Volume12/2-Biodiesel-Production-from-Kapok-Seed.pdf
[9] Santoso MPB, Susatyo EB, Prasetya AT. Sintesis biodiesel dari minyak biji kapuk dengan katalis zeolit sekam padi. Indo. J. Chem. Sci. [Internet]. 2012 Nov [cited 2013 Aug 2];2:98-103. Available from: https://journal.unnes.ac.id/sju/index.php/ijcs/article/view?path=.
[10] Albuquerque MCG, Azevedo DCS, Cavalcante CL, Santamaría-González J, Mérida-Robles JM, Moreno-Tost R, et al. Transesterification of ethyl butyrate with methanol using MgO/CaO catalysts. J. Mol. Catal. A: Chem. [Internet]. 2009 Mar [cited 2013 Jan 15]; 300(1):19-24.. Available from: http://www.sciencedirect.com/science/article/pii/S1381116908004950 DOI: 10.1016/j.molcata.2008.10.033
[2] Leung DYC, Wu X, Leung MKH. A review on biodiesel production using catalyzed transesterification. Appl. Energy. [Internet]. 2010 Apr [cited 2013 Jan 15];87(4):1083-95. Available from: http://www.sciencedirect.com/science/article/pii/S0306261909004346 DOI: 10.1016/j.apenergy.2009.10.006
[3] Maceiras R, Rodrı´guez M, Cancela A, Urréjola S, Sánchez A. Macroalgae: Raw material for biodiesel production. Appl. Energy. [Internet]. 2011 Oct [cited 2013 Jun 14]; 88(10):3318-23. Available from: http://www.sciencedirect.com/science/article/pii/S0306261910004903 DOI: 10.1016/j.apenergy.2010.11.027
[4] Asri NP, Machmudah S, Wahyudiono, Suprapto, Budikarjono K, Roesyadi A, et al. Palm oil transesterification in sub- and supercritical methanol with heterogeneous base catalyst. Chem. Eng. Process. [Internet]. 2013 Oct [cited 2014 Jun 14]; 72:63-7. Available from: http://www.sciencedirect.com/science/article/pii/S0255270113001670 DOI: 10.1016/j.cep.2013.07.003
[5] Suganya T, Nagendra Gandhi N, Renganathan S. Production of algal biodiesel from marine macroalgae Enteromorpha compressa by two step process: Optimization and kinetic study. Bioresour. Technol. [Internet]. 2013 Jan [cited 2014 Mei 14]; 128: 392-400. Available from: http://www.sciencedirect.com/science/article/pii/S0960852412015702 DOI: 10.1016/j.biortech.2012.10.068
[6] Lam MK, Lee KT, Mohamed AR. Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnol. Adv. [Internet]. 2010 Jul [cited 2013 Dec 14]; 28(4):500-18. Available from: http://www.sciencedirect.com/science/article/pii/S0734975010000388 DOI: 10.1016/j.biotechadv.2010.03.002
[7] Sivakumar P, Sindhanaiselvan S, Gandhi NN, Devi SS, Renganathan S. Optimization and kinetic studies on biodiesel production from underutilized Ceiba Pentandra oil. Fuel. Internet]. 2013 Jan [cited 2013 Feb 19]; 103:693-8. Available from: http://www.sciencedirect.com/science/article/pii/S0016236112004498 DOI: 10.1016/j.fuel.2012.06.029
[8] Putri EMM, Rachimoellah M, Santoso N, Pradana F. biodiesel production from kapok seed oil (Ceiba pentandra) through the transesterification process by using CaO as catalyst. Global Journal of Researches in Engineering [Internet]. 2012 Aug [cited 2013 Feb 22]; 12(2):7-12. Available from: https://globaljournals.org/GJRE_Volume12/2-Biodiesel-Production-from-Kapok-Seed.pdf
[9] Santoso MPB, Susatyo EB, Prasetya AT. Sintesis biodiesel dari minyak biji kapuk dengan katalis zeolit sekam padi. Indo. J. Chem. Sci. [Internet]. 2012 Nov [cited 2013 Aug 2];2:98-103. Available from: https://journal.unnes.ac.id/sju/index.php/ijcs/article/view?path=.
[10] Albuquerque MCG, Azevedo DCS, Cavalcante CL, Santamaría-González J, Mérida-Robles JM, Moreno-Tost R, et al. Transesterification of ethyl butyrate with methanol using MgO/CaO catalysts. J. Mol. Catal. A: Chem. [Internet]. 2009 Mar [cited 2013 Jan 15]; 300(1):19-24.. Available from: http://www.sciencedirect.com/science/article/pii/S1381116908004950 DOI: 10.1016/j.molcata.2008.10.033